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À La Mode Component ID: G_riboseC3endo_O3H_O5P_anti_+sc

Component name: (view abbreviated component mmCIF) (view full component mmCIF)

guanosine-5'-phosphate

Component description:

Model constructed for guanosine-5'-phosphate from subcomponents for base, sugar and phosphate. The sugar is ribose in the C3'-endo conformation, and geometries for the gamma torsion angle (synclinal), the chi torsion angle (antiperiplanar), and the C3*-O3* and C5*-O5* bonds are inserted from other models.

Component formula and formula weight:

H10 C10 N5 O8 P1 ( 359.2 grams/mole)

Modeled component diagram:


Modeled component formula and formula weight:

C10 N5 O8 P1 ( 349.1 grams/mole)

Component formal charge: -2


Component canonical SMILES string [Created by the Daylight Toolkit]:

Nc1nc2n(cnc2c(=O)[nH]1)C3OC(COP(=O)([O-])[O-])C(O)C3O

Component exchange SMILES string:

N1(C(=NC2=C(C1=O)N=C(N2C3(C(C(C(C(OP(=O)([O-])[O-])([H])[H])(O3)[H])(O[H])[H])(O[H])[H])[H])[H])N([H])[H])[H]

This model built from À La Mode sub-components:

Subcomponent ID Subcomponent Type Details
gua base Model constructed for guanine with an N9-glycosidic linkage.
ribose_C3endo_O3H_O5P_+sc sugar Model constructed for 1'-amino-ribose in the C3'-endo conformation. the gamma torsion (synclinal), the corresponding O4*-C4*-C5*-O5* torsion, and the C3*-O3* and C5*-O5* bond geometries are inserted from other models.
PO4 phosphate n.a.


Stereochemical Features Table:


Chiral Center Neighbor U Neighbor V Neighbor W Volume [1] Volume E.S.D.
C2* C1* C3* O2* -2.8 0.05
C3* C2* C4* O3* -2.5 0.08
C4* C3* O4* C5* 2.5 0.06


Chiral Center Neighbor U Neighbor V Neighbor W Out-of-plane Angle [2] Out-of-plane Angle E.S.D.
C2* C1* C3* O2* -58.7 1.70
C3* C2* C4* O3* -51.2 2.20
C4* C3* O4* C5* 50.8 1.30

[1] Neighboring atoms U, V and W form vectors with the chiral center. The chiral volume is computed as (UxV)*W
[2] The out-of-plane angle is computed as 90.0 - ACOS(((UxV)*W)/(|UxV||W|))

Bond Distance Table:


Atom 1 Atom 2 Distance E.S.D. Type
N1 C2 1.3717 0.0089 sing
C2 N3 1.3232 0.0096 doub
N3 C4 1.3512 0.0084 sing
C4 C5 1.3792 0.0073 doub
C5 C6 1.4166 0.0092 sing
C6 N1 1.3916 0.0081 sing
C5 N7 1.3867 0.0067 sing
N7 C8 1.3063 0.0077 doub
C8 N9 1.3736 0.0082 sing
N9 C4 1.3751 0.0083 sing
C2 N2 1.3403 0.0096 sing
C6 O6 1.2379 0.0090 doub
C8 H8 n.a. n.a. sing
N2 HA2 n.a. n.a. sing
N2 HB2 n.a. n.a. sing
C1* C2* 1.5301 0.0131 sing
C1* HA1* 1.5160 0.0080 sing
C2* C3* 1.5271 0.0074 sing
C2* HA2* 1.5160 0.0080 sing
C3* C4* 1.5196 0.0121 sing
C3* HA3* 1.5160 0.0080 sing
C4* O4* 1.4489 0.0094 sing
C4* HA4* 1.5160 0.0080 sing
O4* C1* 1.4076 0.0078 sing
C2* O2* 1.4201 0.0094 sing
O2* HAO2* 1.4350 0.0130 sing
C3* O3* 1.4132 0.0049 sing
C5* C4* 1.5065 0.0081 sing
C5* O5* 1.4439 0.0100 sing
C5* HA5* 1.5160 0.0080 sing
C5* HB5* 1.5160 0.0080 sing
P O1P 1.4850 0.0170 doub
P O2P 1.4850 0.0170 sing
P O 1.4850 0.0170 sing
C1* N9 1.4722 0.0124 sing
P O5* 1.5930 0.0100 sing


Bond Angle Table:


Atom 1 Atom 2 Atom 3 Angle E.S.D.
C6 N1 C2 125.09 0.66
N1 C2 N3 123.93 0.56
C2 N3 C4 111.87 0.61
N3 C4 C5 128.61 0.66
C4 C5 C6 118.80 0.68
C5 C6 N1 111.60 0.61
C4 C5 N7 110.76 0.51
C5 N7 C8 104.36 0.59
N7 C8 N9 113.12 0.67
C8 N9 C4 106.33 0.49
N9 C4 C5 105.41 0.42
N3 C4 N9 125.96 0.79
C6 C5 N7 130.42 0.66
N1 C2 N2 116.07 0.91
C6 C2 N2 143.71 0.76
N1 C6 O6 120.01 0.73
C5 C6 O6 128.36 0.66
C1* C2* C3* 101.03 0.80
C2* C3* C4* 102.21 1.01
C3* C4* O4* 104.10 0.66
C4* O4* C1* 109.97 0.70
O4* C1* C2* 107.59 0.65
C1* C2* O2* 108.24 1.82
C3* C2* O2* 110.24 1.94
C2* C3* O3* 113.59 1.53
C4* C3* O3* 112.68 1.76
C5* C4* C3* 115.79 1.39
C5* C4* O4* 109.78 1.07
O5* C5* C4* 110.66 2.05
O1P P O2P 119.60 1.50
O1P P O 108.30 3.20
O2P P O 107.30 3.20


Torsion Angle Table:


Atom 1 Atom 2 Atom 3 Atom 4 Angle E.S.D.
N1 C2 N3 C4 0.69 1.98
C2 N3 C4 C5 359.60 1.63
N3 C4 C5 C6 359.84 1.97
C4 C5 C6 N1 0.43 1.95
C5 C6 N1 C2 359.81 2.66
C6 N1 C2 N3 359.56 3.03
N9 C4 C5 N7 359.75 1.10
C4 C5 N7 C8 0.08 0.93
C5 N7 C8 N9 0.13 0.75
N7 C8 N9 C4 359.71 0.86
C8 N9 C4 C5 0.31 1.00
C6 N1 C2 N2 179.75 2.47
C2 N1 C6 O6 179.98 2.41
C4* O4* C1* C2* 3.53 4.87
O4* C1* C2* C3* 334.37 3.95
C1* C2* C3* C4* 36.70 2.48
C2* C3* C4* O4* 324.20 2.68
C3* C4* O4* C1* 20.45 4.27
C2* C3* C4* C5* 203.61 2.82
C3* C4* C5* O5* 52.19 4.95
O3* C3* C4* C5* 81.27 3.80
O4* C4* C3* O3* 201.87 3.83
O4* C4* C5* O5* 293.22 4.75
C5* C4* O4* C1* 145.01 4.68
C1* C2* C3* O3* 158.39 3.34
O3* C3* C2* O2* 44.06 3.47

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